Electrochemical ammonia oxidation reaction on defect-rich TiO nanofibers: Experimental and theoretical studies
作者：Shuo Zhang，Yanchao Zhao，Liting Yan*，Huimin Jiang，Xue Yang，Yameng Wang，Hexue Song，Xuebo Zhao*
關(guān)鍵字：TiO nanofibers；Self-supporting electrodes；Ammonia oxidation reaction；Oxygen vacancy；Non-noble metal catalyst
論文來源：期刊
具體來源：INTERNATIONAL JOURNAL OF HYDROGEN ENERGY，2022，46 (79) , pp.39208-39215
發(fā)表時間：2022年
Ammonia is a promising platform molecule for the future renewable energy infrastructure owing to its high hydrogen content and carbon-free nature. The development of inexpensive and efficient catalysts for ammonia electro-oxidation reaction (AOR) is essential to ammonia-based economy. In this paper, a self-supporting AOR catalyst of ultra-elongated defective TiO nanofibers grown on Ti foil (TiO/Ti foil) is designed. By the comparisons of electrochemical measurement results, the efficient AOR activity of TiO/Ti foil has been presented in alkaline ammonia solution when the voltage is higher than 0.4 V. Density functional theory (DFT) calculations illustrate that the surface oxygen vacancies in TiO play a vital role in facilitating AOR activity by reducing the energy barrier in the rate-determining *HNNH2 formation step and also promoting N-2 desorption. These results demonstrate that defective TiO is a promising low-cost and stable catalyst for AOR, which is a potential electrode for efficient H-2 production by ammonia electrolysis and direct ammonia fuel cells. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.