Boosting Fast and Stable Alkali Metal Ion Storage by Synergistic Engineering of Oxygen Vacancy and Amorphous Structure
作者：Sheng Wen, Xin Gu*, Xiangwei Ding, Pengcheng Dai, Dongju Zhang, Liangjun Li, Dandan Liu, Xuebo Zhao*
關鍵字：alkali metal ion batteries；amorphous structure；oxygen vacancy；polyanionic compounds；reaction kinetics
論文來源：期刊
具體來源：ADVANCED FUNCTIONAL MATERIALS，2022，32, 6，2106751
發表時間：2022年
Alloy-type anode materials exhibit great promise in alkali metal ion batteries (AMIBs), due to their high theoretical capacities and appropriate operation voltages. Nevertheless, their applications are severely obstructed by large volume expansion upon cycling. Herein, the synergistic cooperation of oxygen vacancy, amorphous structure, and bulky poly- anions in alloy-based phosphates (SnP2O7, BiPO4, and SbPO4)/N-doped carbon are reported for high-performance anode materials of AMIBs. In this composite, bulky polyanions mitigate the structure stress, amorphous structure facilitates the ion transport, and oxygen vacancy changes the electronic structure as confirmed by control experiments and density functional theory calculations. Thus, the electrochemical performances of this composite are greatly improved. Using K-storage performances of SnP2O7 as an example, amorphous and oxygen-deficient SnP2O7-x/N-doped carbon delivers a high specific capacity (376 mAh g(-1) at 0.1 A g(-1)), a stable cycling performance (320.8 mAh g(-1) after 5000 cycles at 1 A g(-1)), and a good rate capability (161.1 mAh g(-1) at 10 A g(-1)). The K storage mechanism of SnP2O7 is identified as a typical two-step process, i.e., a conversion reaction and an alloying reaction