[J. Am. Chem. Soc.] Surface-Initiated Group Transfer Polymerization (SI-GTP) Mediated by Rare Earth Metal Catalysts
作者：Ning Zhang, Stephan Salzinger, Frank Deubel, Rainer Jordan, and Bernhard Rieger
關鍵字：group transfer polymerization, rare earth metal, polymer brushes
論文來源：期刊
具體來源：JACS
發表時間：2012年
We present the first example of a surfaceinitiated group transfer polymerization (SI-GTP) mediated by rare earth metal catalysts for polymer brush synthesis. The experimentally facile method allows rapid grafting of polymer brushes with a thickness of >150 nm in <5 min at room temperature. We show the preparation of common
poly(methacrylate) brushes and demonstrate that SI-GTP is a versatile route for the preparation of novel polymer brushes. The method gives access to both thermoresponsive and proton-conducting brush layers.
http://pubs.acs.org/doi/abs/10.1021/ja3027423?mi=uvozc9&af=R&pageSize=20&searchText=peptide