Exfoliated Graphite Oxide Decorated by PDMAEMA Chains and Polymer Particles
作者：Yongfang Yang*, Jie Wang, Jian Zhang, Jinchuan Liu, Xinling Yang, Hanying Zhao*
關鍵字：Polymer/graphene hybrids; Polymer brush
論文來源：期刊
具體來源：Langmuir, 25 (19), 11808-11814 (2009). DOI: 10.1021/la901441p
發表時間：2009年
Exfoliated graphite oxide (GO) sheets with hydroxyl groups and amine groups on the surface were prepared by modification of graphite. Atom transfer radical polymerization (ATRP) initiator molecules were grafted onto the GO sheets by reactions of 2-bromo-2-methylpropionyl bromide with hydroxyl groups and amine groups. Poly-(2-(dimethylamino)ethyl methacrylate) (PDMAEMA) chains on the surface of GO sheets were synthesized by in-situ ATRP. X-ray photoelectron spectroscopy, thermogravimetric analysis, and transmission electron microscopy (TEM) results all demonstrated that polymer chains were successfully produced. After grafting of PDMAEMA, the dispersity of GO sheets in solvents was improved significantly. Poly(ethylene glycol dimethacrylate-co-methacrylic acid) particles
were deposited on GO sheets via hydrogen bonding between MAA units on polymer particles and amine groups of PDMAEMA. TEM and scanning electron microscopy were used to characterize the structure of the nanocomposites.