Modified β-cyclodextrin microspheres towards the a,pplication in intumscent fire resistance and smoke-suppressing of bio-based poly(L-lactic acid)
作者：Zhang Xiaolei, Yang Yubin, Li Meitong, Sun Yongyan Sun, Liu Fude, Wang Junsheng, Yang Jinjun
關鍵字：Fire resistance, PLLA, Beta-CD
論文來源：期刊
具體來源：International Journal of Biological Macromolecules
發表時間：2023年
In this work, the β-cyclodextrin (β-CD) was modified by a phosphazene compound to prepare a novel amorphous derivate (β-CDCP), which was combined with the ammonium polyphosphate (APP) as a synergistic flame retardant (FR) of the bio-based poly(L-lactic acid) (PLA). The effects of the APP/β-CDCP on the thermal stability, combustion behavior, pyrolysis process, fire resistance performance and crystallizability of the PLA were investigated comprehensively and in depth by thermogravimetric (TG) analysis, limited oxygen index (LOI)
analysis, UL-94 test, cone calorimetry measurement, TG-infrared (TG-IR), scanning electron microscopy-energy dispersive spectrometer, Raman spectroscopy, pyrolysis-gas chromatography/mass spectrometry and differential scanning calorimetry. The PLA/5%APP/10%β-CDCP showed a highest LOI of 33.2 %, passed V-0 rating and exhibited self-extinguish phenomenon in the UL-94 test. Also, it presented a lowest peak of heat release rate, total heat release, peak of smoke production rate and total smoke release, and a highest char yield treated by cone calorimetry analysis. In addition, the 5%APP/10%β-CDCP shortened significantly crystallization time and enhanced crystallization rate of the PLA. Gas phase and intumescent condensed phase fire proofing mechanisms are proposed to elucidate enhanced fire resistance in this system in detail.