Kinetic Study on the Melt Compounding of PP/Multi-Walled Carbon Nanotube Composites. Journal of Polymer Science Part B: Polymer Physics, 2009, 47(3), 608-618.
writer：Defeng Wu, Yurong Sun, Liang Wu, Ming Zhang.
keywords：carbon nanotubes; polypropylene; composites; kinetics.
source：期刊
specific source：Journal of Polymer Science Part B: Polymer Physics
Issue time：2009年
Journal of Polymer Science Part B: Polymer Physics, 2009, 47(3), 608-618.
ABSTRACT:
The multi-walled carbon nanotubes/polypropylene nanocomposites (PP/CNTs) were prepared by melt mixing using maleic anhydride grafted polypropylene (mPP) as the compatibilizer. The effect of mPP on dispersion of CNTs was then studied using the tool of rheology, aiming at relating the viscoelastic behaviors to the mesoscopic structure of CNTs. To further explore the kinetics of hybrid formation, a multilayered sample with alternatively superposed neat mPP and binary PP/CNTs microcomposites (without addition of mPP) sheets was prepared and experienced dynamic annealing in the small amplitude oscillatory shear flow. The results show that melt blending CNTs with PP can only yield the composites with micro-scale dispersion of CNTs, while adding mPP promotes nano-scale dispersion of CNTs as smaller bundles or even as individual nanotubes, reducing percolation threshold as a result. However, the values of apparent diffusivities of the composites are in same order with that of self-diffusion coefficients of the neat PP, indicating that the presence of detached CNTs nearly does not inhibit PP chain motion. Hence the activation energy of hybrid formation is close to the self-diffusion of PP. This also indicates that although addition of mPP can improve the compatibility between CNTs and PP thermodynamically, those dynamic factors, such as shear flow, however, may be the dominant role on hybrid formation.
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