Polymeric Salphen-Phthalocyanine Dinuclear Metal Complexes for Activation of Molecular Oxygen
writer：Rong-Min Wang, Er-Xia Hao, Guo-Rui Shen, Yu-Feng He, Zi-Qiang Lei
keywords：polymeric dinuclear metal complex;polyphthalocyanines; salphen schiff base metal complexes;sheet polymer; molecular oxygen; catalytic oxidation
source：期刊
specific source：Wiley Periodicals Inc. J Appl Polym Sci 111: 1999–2005, 2009
Issue time：2009年
The polymeric Salphen Schiff base-phthalocyanine Co-Cu dinuclear metal complex (PSalphenCo-PcCu) was designed and synthesized through interfacial
condensation polymerization. The new sheet polymeric dinuclear metal complex has been characterized by IR spectra, UV-visible spectra, scanning electron microscopy with energy dispersive X-ray analysis and thermogravimetry
analysis. Its catalytic activity for activation of molecular oxygen was investigated by using cumene as substrate without any additive in mild condition. The aerobic oxidation of cumene catalyzed by PSalphenCo-PcCu proved to be a simple and efficient method for obtaining cumene hydroperoxide in a high selectivity.