【30 RSC Advances】 Striking influence of NiO catalyst diameter on the carbonization of polypropylene into carbon nanomaterials and their high performance in the adsorption of oils
作者：Jiang Gong, Jie Liu*, Xuecheng Chen, Zhiwei Jiang, Xin Wen, Ewa Mijowska, Tao Tang*
關鍵字：carbon nanomaterials, NiO catalyst
論文來源：期刊
具體來源：RSC Advances 4 (2014) 33806-33814
發表時間：2014年
Recently, there has been intense interest in the conversion of plastics into high value-added carbon nanomaterials (CNMs), however, the effect of catalyst diameter on the formation of CNMs is still ambiguous. Herein, uniform NiO catalysts with different diameter (18–227 nm) were firstly prepared by a sol–gel combustion synthesis method and calcination at different temperatures. Subsequently, the combined organically-modified montmorillonite (OMMT)/NiO catalyst was used to catalyze carbonization of polypropylene (PP, selected as an example of plastics) into CNMs at 700 °C. The effect of NiO catalyst diameter on the yield, morphology, microstructure, phase structure, thermal stability and texture properties of CNMs including sponge-like cup-stacked carbon nanotubes (CS-CNTs) and carbon fibers were investigated by scanning electron microscopy, transmission electron microscopy (TEM), high-resolution TEM, X-ray diffraction, Raman spectroscopy, thermal gravimetric analysis and N2 sorption. Besides, the effects of NiO catalyst diameter on the coalescence and reconstruction of NiO particles were explored. It was demonstrated that NiO catalysts with small diameter were more susceptible to coalescence and reconstruction into rhombic shape, which facilitated the growth of long, straight CS-CNTs. Finally, the obtained sponge-like CS-CNTs were found to show high performance in the adsorption of diesel, vegetable oil, kerosene and mineral oil with good recycling performance. It is believed that this work will contribute to the conversion of waste plastics into high value-added CNMs.