Construction of a heterojunction with fast charge transport channels for photocatalytic hydrogen evolution via a synergistic strategy of Co-doping and crystal plane modulation
writer：Wang, YY (Wang, Yanyun) [1] ; Liang, S (Liang, Shuang) [2] ; Zuo, CJ (Zuo, Changjiang) [1] ; Fang, H
keywords：CARBON NITRIDECDSNANORODSG-C3N4
source：期刊
Issue time：2023年
Carrier spatial separation efficiency and active electron density are the key factors affecting photocatalytic hydrogen evolution activity. Heterojunction catalysts with fast charge separation and directed electron transport systems were successfully prepared by a synergistic modification strategy of transition metal (Co) doping and crystal plane modulation. The optimized electronic structure and enhanced reaction kinetics enabled unidirectional electron transfer. Photocatalytic results show that CdS(002)/Co-C3N4 exhibits remarkable hydrogen evolution activity (991.2 mu mol h(-1) g(-1)) in the absence of a co-catalyst, which is 37.0 and 3.4 times higher than that of C3N4 (26.8 mu mol h(-1) g(-1)) and Co-C3N4 (294.6 mu mol h(-1) g(-1)), respectively. Density functional theory (DFT) calculations indicate that the enhanced catalytic activity of CdS(002)/Co-C3N4 is attributed to the reduced electron-hole recombination rate and the increased electron density at the active site. This work provides a new idea for the design of photocatalysts with directed charge transport channels from the perspective of re-optimizing heterojunctions.