Macromolecular Self-assembly Based on Inclusion Complexation of Cyclodextrins
作者：Mingyu Guo, Ming Jiang*
關(guān)鍵字：cyclodextrins ; self-assembly ; inclusion complexation
論文來源：期刊
具體來源：Prog. Chem. 2007, 19, 557-566.
發(fā)表時(shí)間：2007年
Recent progresses in molecular self2assembly based on the inclusion complexation between cyclodextrins and various guest macromolecules have been reviewed , which include ( 1) polyrotaxanes (molecular necklace ) , polypseudorotaxanes , bis (polypseudorotaxane) s or bis (polyrotaxane) s , molecular tubes or bis (molecular tube) s and supramolecular hydrogels induced by the complexation between cyclodextrins or their dimers and the polymer guests including linear , comb , multi2arms star or hyperbranched ones ; (2) linear or hyperbranched supramolecular polymers prepared by the self2assembly of bridged cyclodextrins and their bridged guest molecules ; (3) intelligent systems showing
stimuli responsive properties including temperature , pH , light or guest molecules ; (4) polymeric micelles and hollow spheres made in water by the inclusion between a linear hydrophilic polymer containing cyclodextrin as side groups and a linear hydrophobic polymer with adamantine appendants. In addition , the potential applications of the resultant
assemblies are discussed.