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Synthesis and characteristics of octacarboxy-metallophthalocyanines

資料類型：

PDF文件

關(guān)鍵詞：

octacarboxy-metallophthalocyanine dyes electrochemical properties

資料大小：

1860K

所屬學(xué)科：

分子表征

來(lái)源：

ICAFPM 2011先進(jìn)纖維與聚合物材料國(guó)際學(xué)術(shù)會(huì)議（2011.8.15~17，上海）

簡(jiǎn)介：

Aseriesofoctacarboxy-metallophthalocyaninedyes,i.e.,MnOCPc,FeOCPcandZnOCPcwithdifferentcentralmetalionsweredesignedandsynthesizedundermicrowaveirradiation.Theeffectsoftheintroductionofdifferentmetalionswithvariant3dorbitals(3d5,3d6,3d10,respectively)inthecentreofthephthalocyanineringsonthethermal,spectral,andelectrochemicalpropertiesofoctacarboxy-metallophthalocyanineswereinvestigatedandevaluated.TheresultsshowedthatZnOCPcwithclosed-shellmetalionandFeOCPcwithopen-shellmetalionhadexcellentthermalproperty.However,MnOCPcwithhalf-full-shellmetalionhadalowestdecompositiontemperatureandlargestQbandred-shifted.Bytheoreticalcalculation,theenergygapsofMnOCPc,FeOCPcandZnOCPcwere0.31,0.37and0.32V,respectively.

作者：

JIN Lin, CHEN Wei, WANG Yang, CHEN Dajun

上傳時(shí)間：

2011-10-20 13:27:57

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