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Soft nanocomposite materials with novel organic/inorganic network structures

資料類型：

PDF文件

關鍵詞：

nanocomposite clay hydrogel network mechanical property

資料大?。?/td>

2594K

所屬學科：

分子表征

來源：

ICAFPM 2011先進纖維與聚合物材料國際學術會議（2011.8.15~17，上海）

簡介：

Newtypesofpolymerhydrogelsandpolymernanocomposites,i.e.,nanocompositegels(NCgels)andsoft,polymernanocomposites(M-NCs),withnovelorganic/inorganicnetworkstructureshavebeenfabricated.BothNCgelsandM-NCsweresynthesizedbyin-situfree-radicalpolymerizationinthepresenceofexfoliatedclayplateletsinaqueoussystemsandwereobtainedinvariousformsandsizeswithawiderangeofclaycontents.Here,disk-likeinorganicclaynanoparticlesactasmulti-functionalcrosslinkerstoformnewtypesofnetworksystems.NCgelshaveextraordinaryoptical,mechanical,andswelling/deswellingproperties,aswellasanumberofnewcharacteristicsrelatingtoopticalanisotropy,polymer/claymorphology,biocompatibility,stimuli-sensitivesurfaces,micro-patterning,etc.TheM-NCsalsoexhibitdramaticimprovementsinopticalandmechanicalpropertiesincludingultra-highreversibleextensibilityandwell-definedyieldingbehavior,despitetheirhighclaycontents.Thus,theseriousdisadvantages(intractability,mechanicalfragility,opticalturbidity,poorprocessingability,lowstimulussensitivity,etc.)associatedwiththeconventional,chemically-crosslinkedpolymericmaterialswereovercomeinNCgelsandM-NCs.

作者：

HARAGUCHI Kazutoshi

上傳時間：

2011-10-18 12:57:36

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