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褰撳墠浣嶇疆錛?棣栭〉 >> 璧勮 >> 鍖栧伐 >> 琛屼笟鍔ㄦ?/a> >> 姝ｆ枃

寮鍙?/span>楂?/span>鏁?/span>鐨?/span>鐢?/span>瑙?/span>姘?/span>鍒?/span>姘?/span>鏂?/span>娉?/span>鏄?/span>瀹?/span>鐜?/span>鏈?/span>鏉?/span>姘?/span>緇?/span>嫻?/span>鐨?/span>鍏?/span>閿?/span>銆?/span>鍦?/span>鐢?/span>鍌?/span>鍖?/span>鏉?/span>鏂?/span>鐨?/span>鐮?/span>絀?/span>棰?/span>鍩?/span>涓?/span>錛?/span>浼?/span>緇?/span>鐨?/span>閾?/span>鍩?/span>鐢?/span>鍌?/span>鍖?/span>鍓?/span>鐢?/span>浜?/span>浠?/span>鏍?/span>鏄?/span>璐?/span>鍜?/span>鍘?/span>鏉?/span>鏂?/span>紼緙?/span>錛?/span>闄?/span>鍒?/span>浜?/span>鍏?/span>澶?/span>瑙?/span>妯?/span>搴?/span>鐢?/span>銆?/span>閫?/span>榪?/span>褰?/span>鎴?/span>Pt鍗?/span>鍘?/span>瀛?/span>鎴?/span>鍥?/span>綈?/span>錛?/span>鍙?/span>浠?/span>鍦?/span>淇?/span>鎸?/span>媧?/span>鎬?/span>鐨?/span>鍚?/span>鏃?/span>鏄?/span>钁?/span>鍑?/span>灝?/span>Pt鐨?/span>浣?/span>鐢?/span>銆?/span>鑰?/span>鐩?/span>瀵?/span>搴?/span>鐨?/span>杞?/span>浣?/span>鏉?/span>鏂?/span>鍒?/span>闇瑕?/span>鍏?/span>鍏?/span>涓?/span>瀵?/span>緙?/span>闄?/span>浣?/span>鍜?/span>楂?/span>瀵?/span>鐢?/span>鎬?/span>錛?/span>浠?/span>鑰?/span>鏈?/span>鍒?/span>浜?/span>媧?/span>鎬?/span>鐗?/span>璐?/span>鐨?/span>璐?/span>杞?/span>鍜?/span>鐢?/span>鑽?/span>鐨?/span>浼?/span>杈?/span>銆?/span> 榪?/span>鏃?/span>錛?/span>鍚?/span>鏋?/span>澶?/span>瀛?/span>閮?/span>浼?/span>娑?/span>鏁?/span>鎺?/span>鍜?/span>鐢?/span>瀹?/span>浼?/span>鏁?/span>鎺?/span>鍥?/span>闃?/span>鍦?/span>銆?/span>Advanced Functional Materials銆?/span>鏈?/span>鍒?/span>涓?/span>鍙?/span>琛?/span>浜?/span>棰?/span>涓?/span>鈥?/span>Highly Conductive Amorphous Pentlandite Anchored with Ultrafine Platinum Nanoparticles for Efficient pH-Universal Hydrogen Evolution Reaction鈥?/span>鐨?/span>鏂?/span>绔?/span>錛?/span>DOI錛?/span>10.1002/adfm.202105372錛?/span>銆?/span>璇?/span>鏂?/span>绔?/span>閫?/span>榪?/span>涓縐?/span>鏂?/span>棰?/span>鐨?/span>緇?/span>鏋?/span>璁?/span>璁?/span>鏂?/span>娉?/span>鍚?/span>鎴?/span>鍑?/span>涓縐?/span>鍏?/span>pH楂?/span>鏁?/span>鏋?/span>姘?/span>鐢?/span>鍌?/span>鍖?/span>鍓?/span>銆?/span>閫?/span>榪?/span>Pt鍗?/span>鍘?/span>瀛?/span>鍜?/span>鍥?/span>綈?/span>鐨?/span>鍒?/span>澶?/span>錛?/span>鏄?/span>钁?/span>闄?/span>浣?/span>浜?/span>Pt鐨?/span>鍚?/span>閲?/span>錛?/span>騫?/span>淇?/span>鎸?/span>浜?/span>涓?/span>甯?/span>鍞?/span>Pt/C鐩?/span>褰?/span>鐨?/span>鍌?/span>鍖?/span>鎬?/span>鑳?/span>銆?/span>鍚?/span>鏃?/span>錛?/span>闈?/span>鏅?/span>鎬?/span>Fe5Ni4S8(FNS)鍩?/span>浣?/span>鍏?/span>鍏?/span>楂?/span>瀵?/span>鐢?/span>鎬?/span>鍜?/span>涓?/span>瀵?/span>鐨?/span>緙?/span>闄?/span>浣?/span>錛?/span>鏈?/span>鍒?/span>浜?/span>Pt鍗?/span>鍘?/span>瀛?/span>鍜?/span>鍥?/span>綈?/span>鐨?/span>閿?/span>瀹?/span>銆?/span>鍒?/span>鏁?/span>鍜?/span>淇?/span>鎶?/span>錛?/span>浠?/span>鍙?/span>蹇?/span>閫?/span>鐨?/span>鐢?/span>鑽?/span>杞?/span>縐?/span>錛?/span>浠?/span>鑰?/span>鍗?/span>鍚?/span>鎻?/span>楂?/span>鍌?/span>鍖?/span>鎬?/span>鑳?/span>銆?/span>


鍥?/span>1.錛?/span>a錛?/span>Bm-5d-Pt鍌?/span>鍖?/span>鍓?/span>鐨?/span>TEM鍥?/span>鍍?/span>銆?/span>錛?/span>b錛?/span>HRTEM鍥?/span>鍍?/span>銆?/span>錛?/span>c, d錛?/span>HADDF-STEM鍥?/span>鍍?/span>鍜?/span>錛?/span>e, f錛?/span>鍏?/span>绱?/span>鏄?/span>灝?/span>鍥?/span>銆?/span>

鍥?/span>2. 涓?/span>鍚?/span>鐢?/span>鍌?/span>鍖?/span>鍓?/span>鐨?/span>錛?/span>a, d, g錛?/span>HER鏋?/span>鍖?/span>鏇?/span>綰?/span>銆?/span>錛?/span>b, e, h錛?/span>鍦?/span>10 mA cm-2瀵?/span>搴?/span>鐨?/span>榪?/span>鐢?/span>浣?/span>鍜?/span>錛?/span>c, f, i錛?/span>鐩?/span>搴?/span>鐨?/span>Tafel鍥?/span>銆?/span>


鍥?/span>3.錛?/span>a錛?/span>FNS錛?/span>311錛?/span>鍜?/span>錛?/span>b錛?/span>Pt-FNS錛?/span>311錛?/span>鐨?/span>Bader鐢?/span>鑽?/span>鍒?/span>鏋?/span>銆?/span>鐢?/span>鑽?/span>鐨?/span>鍗?/span>浣?/span>鏄?/span>|e|銆?/span>錛?/span>c錛?/span>FNS鍜?/span>Pt-FNS琛?/span>闈?/span>涓?/span>鐨?/span>HER鑷?/span>鐢?/span>鑳?/span>鍥?/span>鍜?/span>錛?/span>d錛?/span>FNS鍜?/span>Pt-FNS姘?/span>鍚?/span>闄?/span>浣?/span>鐐?/span>鐨?/span>璁?/span>綆?/span>鎬?/span>瀵?/span>搴?/span>銆?/span>錛?/span>d錛?/span>涓?/span>鐨?/span>鎻?/span>鍥?/span>鏄?/span>紺?/span>浜?/span>FNS鍜?/span>Pt-FNS涓?/span>鐨?/span>姘?/span>鍚?/span>闄?/span>浣?/span>緗?/span>銆?/span>緇?/span>鑹?/span>銆?/span>鐏?/span>鑹?/span>銆?/span>榛?/span>鑹?/span>鍜?/span>钃?/span>鑹?/span>鍒?/span>鍒?/span>浠?/span>琛?/span>閾?/span>銆?/span>闀?/span>銆?/span>紜?/span>鍜?/span>閾?/span>鍘?/span>瀛?/span>銆?/span>


璇?/span>璁?/span>鏂?/span>鐨?/span>絎?/span>涓浣?/span>鑰?/span>涓?/span>鍚?/span>鏋?/span>澶?/span>瀛?/span>鏉?/span>鏂?/span>縐?/span>瀛?/span>涓?/span>宸?/span>紼?/span>瀛?/span>闄?/span>鍦?/span>璇?/span>鍗?/span>澹?/span>鐢?/span>寮?/span>鐞?/span>鏃?/span>錛?/span>閫?/span>璁?/span>浣?/span>鑰?/span>涓?/span>閮?/span>浼?/span>娑?/span>鏁?/span>鎺?/span>鍜?/span>鐢?/span>瀹?/span>浼?/span>鏁?/span>鎺?/span>銆?/span>


鐩?/strong>鍏?/strong>閾?/strong>鎺?/strong>

https://doi.org/10.1002/adfm.202105372

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